Here is a list of PNP programs for every province in Canada. Keep in mind each province sets its own rules for it’s PNP program so they can be very different.
Qubec - Does not participate in Express Entry
Newfoundland and Labrador
Prince Edward Island
If you want to claim extra points of your PNP nomination when applying for PR through Express Entry or some other program then you must first satisfy the requirements for the chosen province’s PNP program and get nominated by them.
If you are accepted into a PNP program then you can choose the name of the province in your Express Entry profile under the section for provincial nomination. Then contact your province and provide them your “Express Entry profile number” which they will then use to send confirmation to CIC.
The nomination will then show up on your MyCIC profile and you will have 30 days to accept or reject it. Also if you do your PR using PNP then you may be required to live in that province for up to 2 years.